Crystallization of a Keplerate-type polyoxometalate into a superposed kagome-lattice with huge channels.
نویسندگان
چکیده
Crystal structures of two Sr(2+) salts of the Keplerate-type polyoxometalate, [Mo(VI)(72)Mo(V)(60)O(372)(CH(3)COO)(30)(H(2)O)(72)](42-), have been determined by single crystal X-ray diffraction. One compound exhibits a superposed kagome-lattice with huge channels whose diameters measure approximately 3.0 nm, while the arrangement of the Keplerate anions in the other compound approximates to a distorted cubic close packing.
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عنوان ژورنال:
- Dalton transactions
دوره 41 33 شماره
صفحات -
تاریخ انتشار 2012